Study on the 4-(2-Pyridylazo)-resorcinol and 1-(2-Pyridylazo)-2-naphthol as Metal Indicator for Copper
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Liquid chromatography of palladium and non-ferrous metal chelates with 1-(2-pyridylazo)-2-naphthol.
1-(2-Pyridylazo)-2-naphthol has been used for extraction concentration of palladium, copper, cobalt and nickel from aqueous solutions and subsequent separation of the chelates obtained, by means of high-pressure liquid chromatography. A technique for determining microamounts of palladium in aqueous solutions in the presence of 100-fold ratio of copper and 80-fold ratio of cobalt has been develo...
متن کاملHighly copper(II) ion-selective transport through liquid membrane containing 1-(2-pyridylazo)-2-naphthol.
often an important process in industry and chemical analysis. Liquid-membrane transport in which the extraction and stripping operations are combined in a single process reduces the solvent inventory requirement, and also allows the use of expensive and highly selective extractions, which otherwise would be uneconomic in solvent extractants. For these reasons, liquid-membrane transport has attr...
متن کاملSPECTROPHOTOMETRIC- STUDY OF THERMODYNAMICS OF SOME HEAVY METAL COMPLEXES OF 4-(2 - PYRIDYLAZO) RESORCINOL IN BINARY ACETONITRILEDIMETHYLFORMAMIDE MIXTURES
The complexation reactions between 4-(2-pyridy1azo)-resorcinol and Cd ,H g and Pb io ns have been investigated in acetonitrile-dimethyEomamide mixtures at various temperatures using a spectrophotometric technique. The stoichiometry and the formation constants of the complexes formed in solution were calculated by computer refinement of absorbance-mole ratio data using nonlinear least-square ...
متن کاملPolymer-Controlled Synthesis of 1-(2-Pyridylazo)-2-Naphthol Hierarchical Architectures
The self-assembly of organic 1-(2-pyridylazo)-2-naphthol (PAN) into hierarchical architectures, such as microfibers, microrods, and sheaflike structures, in solution was successfully achieved by reprecipitation method with the assistance of thermoresponsive diblock copolymer poly(N,N-dimethylacrylamide)-b-poly(N-isopropylacrylamide) (PDMA-b-PNIPAM). It was found that the morphology modification...
متن کاملIon-association complexes of gallium(III)-4-(2-pyridylazo)-resorcinol anionic chelates and dicationic tetrazolium reagents.
The formation and liquid-liquid extraction of ion-association complexes between gallium(III)-4-(2-pyridylazo)resorcinol (PAR) anionic chelates and cations of four ditetrazolium chlorides (DT2+) were studied: Neotetrazolium chloride (NTC), Blue Tetrazolium chloride (BTC), Nitro Blue Tetrazolium chloride (NBT) and Tetranitro Blue Tetrazolium chloride (TNBT). The optimum extraction-spectrophotomet...
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ژورنال
عنوان ژورنال: Nippon kagaku zassi
سال: 1964
ISSN: 0369-5387,2185-0917
DOI: 10.1246/nikkashi1948.85.9_549